Both ionic and covalent bromides are known for metals in oxidation state +3 (e.g. The remaining polyatomic ions are all negatively-charged and, therefore, are classified as anions. Cations are ions that are positively charged. Specific highly brominated molecules can also be added that participate in the polymerisation process For example, tetrabromobisphenol A can be added to polyesters or epoxy resins, where it becomes part of the polymer. As a strong oxidising agent, bromine is incompatible with most organic and inorganic compounds. Bromine (Br) forms a anion (negative charge) because it is a most likely ion element type of ion symbol of WebFormula and structure: Sodium bromide chemical formula is NaBr and the molar mass is 102.89 g mol-1.It can be found hydrated by one (monohydrate NaBr) or two (duhydrate NaBr) water molecules. It is not an ionic compound; it belongs to the category of covalent compounds discuss elsewhere. The principal reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, and nucleophilic substitution. The amount of hydrogen phosphate ions\(\ce{HPO4^{2}}\) and \(\ce{H2PO4^{}}\)in seawater is very low, but they are present in higher amounts in blood, where they also affect acid-base properties. The second table gives the same information for some common monoatomic anions.\r\n
Some Common Monoatomic Cations
\r\n\r\n
\r\n
Family
\r\n
Element
\r\n
Ion Name
\r\n
\r\n
\r\n
IA
\r\n
Lithium
\r\n
Lithium cation
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\r\n
\r\n
\r\n
Sodium
\r\n
Sodium cation
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\r\n
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\r\n
Potassium
\r\n
Potassium cation
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\r\n
\r\n
IIA
\r\n
Beryllium
\r\n
Beryllium cation
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\r\n
\r\n
\r\n
Magnesium
\r\n
Magnesium cation
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\r\n
\r\n
\r\n
Calcium
\r\n
Calcium cation
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\r\n
\r\n
\r\n
Strontium
\r\n
Strontium cation
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\r\n
Barium
\r\n
Barium cation
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\r\n
\r\n
IB
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Silver
\r\n
Silver cation
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\r\n
\r\n
IIB
\r\n
Zinc
\r\n
Zinc cation
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\r\n
\r\n
IIIA
\r\n
Aluminum
\r\n
Aluminum cation
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\r\n\r\n
\r\n
Some Common Monoatomic Anions
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\r\n
Family
\r\n
Element
\r\n
Ion Name
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\r\n
\r\n
VA
\r\n
Nitrogen
\r\n
Nitride anion
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\r\n
\r\n
\r\n
Phosphorus
\r\n
Phosphide anion
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\r\n
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VIA
\r\n
Oxygen
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Oxide anion
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Sulfur
\r\n
Sulfide anion
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VIIA
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Fluorine
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Fluoride anion
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Chlorine
\r\n
Chloride anion
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\r\n
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Bromine
\r\n
Bromide anion
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\r\n
\r\n
\r\n
Iodine
\r\n
Iodide anion
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\r\n\r\n
\r\nIts more difficult to determine the number of electrons that members of the transition metals (the B families) lose. Write the chemical formula for the ionic compound formed by each pair of ions. (A discussion of the theory supporting the favored status of noble gas electron numbers reflected in these predictive rules for ion formation is provided in a later chapter of this text.). 7. Example \(\PageIndex{2}\): Formation of Ions. Because most metals form cations and most nonmetals form anions, formulas typically list the metal first and then the nonmetal. 13. Write the chemical formula for the ionic compound formed by each pair of ions. Chronic exposure may lead to frequent bronchial infections and a general deterioration of health. We could write the chemical formula for this ionic compound as \(\ce{MgClCl}\), but the convention is to use a numerical subscript when there is more than one ion of a given type\(\ce{MgCl2}\). If more than one of a particular polyatomic ion is needed to balance the charge, the entire formula for the polyatomic ion must be enclosed in parentheses, and the numerical subscript is placed outside the parentheses. Moving from the far right to the left on the periodic table, elements often form anions with a negative charge equal to the number of groups moved left from the noble gases. Our tests have shown that this is indeed the case. This method is shown schematically in Figure 3.3.2. While both the nitrate ion and the sulfate ion share an "-ate" suffix, the former contains three oxygens, but the latter contains four. A single suffix, "-ide," is insufficient for distinguishing the names of the anions in a related polyatomic series. Because the number of protons remains unchanged when an atom forms an ion, the atomic number of the element must be 13. The bromine industry is about one-hundredth the size of the chlorine industry. Therefore, the proper formula for this ionic compound is \(\ce{MgO}\). Second, if you recognize the formula of a polyatomic ion in a compound, the compound is ionic. To become stable (have a complete octet), it either has to lose five electrons or gain three. Refractory oxides tend to be only partially fluorinated, but here the derivatives KBrF4 and BrF2SbF6 remain reactive. silver bromide for photography). Language links are at the top of the page across from the title. For example, CaBr2 contains a metallic element (calcium, a group 2A metal) and a nonmetallic element (bromine, a group 7A nonmetal). [43] Neutrophil myeloperoxidase can use H2O2 and Br to brominate deoxycytidine, which could result in DNA mutations. Web2. It reacts violently with water and explodes on contact with flammable materials, but is a less powerful fluorinating reagent than chlorine trifluoride. WebIn the second row, write the symbol for the ion that an atom of bromine is mostly likely to form and then decide what type of ion it is. This is then removed with a blast of steam or air, and is then condensed and purified. [30], Nearly all elements in the periodic table form binary bromides. the ratio of each kind of ion in the compound, Table \(\PageIndex{1}\): Some Polyatomic Ions, source@https://2012books.lardbucket.org/books/introduction-to-chemistry-general-organic-and-biological, status page at https://status.libretexts.org. Thus, \(\ce{NaCl}\) is the chemical formula for sodium chloride, which is a concise way of describing the relative number of different ions in the compound. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. You can often determine the charge an ion normally has by the elements position on the periodic table: The alkali metals (the IA elements) lose a single electron to form a cation with a 1+ charge. The reaction passes through a short-lived strongly electrophilic bromonium intermediate. Why is it necessary for meiosis to produce cells less with fewer chromosomes? Expert Help. It is the forty-sixth most abundant element in Earth's crust. The formula for an ionic compound follows several conventions. WebFor example, in the first row decide whether Sc3+ is a cation or anion. (b) A sodium cation (Na+) has lost an electron, so it has one more proton (11) than electrons (10), giving it an overall positive charge, signified by a superscripted plus sign. WebSelect all that apply. Silver bromide is very insoluble in water and is thus often used as a qualitative test for bromine. It is significantly more abundant in the oceans, resulting from long-term leaching. WebDietary cation-anion difference (DCAD) has been defined as the difference in milliequivalents of cations (Na, K) and anions (Cl, S) per kilogram Consequently, the use of anionic salts has become a popular method to prevent hypocalcemia in dairy cattle. The \(\ce{NH4}\) in the formula represents the ammonium ion, \(\ce{NH4^{+}}\), which indicates that this compound is ionic. These methods work best when the bromide product is stable to hydrolysis; otherwise, the possibilities include high-temperature oxidative bromination of the element with bromine or hydrogen bromide, high-temperature bromination of a metal oxide or other halide by bromine, a volatile metal bromide, carbon tetrabromide, or an organic bromide. (Br+ is given off). It oxidises iodine to iodine pentoxide and benzene to 1,4-benzoquinone; in alkaline solutions, it gives the hypobromite anion. In contrast, seawater is principally a 3% sodium chloride solution, over three times the concentration in blood. Knowing this lets us use the periodic table to identify the element as Al (aluminum). [49] Today, bromine is transported in large-capacity metal drums or lead-lined tanks that can hold hundreds of kilograms or even tonnes of bromine. Chlorine atom cation: 1: Br-Bromine atom anion-1: Br + Bromine atom cation: 1: I-Iodine atom anion-1: I + Iodine atom cation: 1: HF-hydrogen fluoride anion-1: HF + (Remember that the convention for writing formulas for ionic compounds is not to include the ionic charge.) After all, both liquids have ionic compounds dissolved in them. In fact, many of these elements lose a varying number of electrons so that they form two or more cations with different charges.\r\n
The electrical charge that an atom achieves is sometimes called its state. In fact, transition metals and some other metals often exhibit variable charges that are not predictable by their location in the table. And all of them form an anion with a single negative charge. Two examples are shown below: There are two ways to recognize ionic compounds. [citation needed] The element is liberated by halogen exchange, using chlorine gas to oxidise Br to Br2. The exceptions are decidedly in the minority and stem in each case from one of three causes: extreme inertness and reluctance to participate in chemical reactions (the noble gases, with the exception of xenon in the very unstable XeBr2); extreme nuclear instability hampering chemical investigation before decay and transmutation (many of the heaviest elements beyond bismuth); and having an electronegativity higher than bromine's (oxygen, nitrogen, fluorine, and chlorine), so that the resultant binary compounds are formally not bromides but rather oxides, nitrides, fluorides, or chlorides of bromine. Cations (positively-charged ions) and anions (negatively-charged ions) are formed when a metal loses electrons, and a nonmetal gains those electrons. WebIn Sections 3.10.1 ,B, electrophilic reagents (e.g., the bromonium ion [Br + ]), generated by the reaction of diatomic bromine (Br 2) and aluminum bromide (AlBr 3 )], were shown to A 0.9% solution of sodium chloride approximates the salt concentration found in blood. The formula for lithium bromide is \(\ce{LiBr}\). The formula for an ionic compound follows several conventions. The nucleus comprises a very small fraction of the total volume of the atom. The similarity may be more than mere coincidence; many scientists think that the first forms of life on Earth arose in the oceans. Web2 ions the latter, in any case, are much less stable than the bifluoride ions (HF 2) due to the very weak hydrogen bonding between hydrogen and bromine, though its salts with very large and weakly polarising cations such as Cs + and NR + Chlorine does not exist as a diatomic element in this compound. For each pair of elements, determine the charge for their ions and write the proper formula for the resulting ionic compound between them. Both oxygen and fluorine are nonmetals. Remember that in an ionic compound, the component species are ions, not neutral atoms, even though the formula does not contain charges. Polyatomic ions have defined formulas, names, and charges that cannot be modified in any way. We will need two nitrate ions to balance the charge on each calcium ion. WebAnion = Any ion with a negative charge Cation = Any ion with a positive charge Anions and cations combine to form ionic compounds so that the charges cancel out. Thus, the formula for this ionic compound is \(\ce{Fe2O3}\). Before the Montreal protocol in 1991 (for example) an estimated 35,000 tonnes of the chemical were used to control nematodes, fungi, weeds and other soil-borne diseases. A 2014 study suggests that bromine (in the form of bromide ion) is a necessary cofactor in the biosynthesis of collagen IV, making the element essential to basement membrane architecture and tissue development in animals. Write the symbol for each ion and name them. Therefore, for the resulting compound to be neutral, two bromine anions must combine with one magnesium cation to form magnesium bromide ([latex]\text{MgBr}_2[/latex]). Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Historically, the therapeutic dose of bromide is about 3 to 5grams of bromide, thus explaining why chronic toxicity (bromism) was once so common. scandium Sc cation O anion sulfur Ocation anlon nuorine cation anion Study Resources. Why do the chemical formulas for some ionic compounds contain subscripts, while others do not. Sodium bromide is formed by one sodium cation Na + and one bromide anion Br-which are joined through an ionic bond. Each ion is surrounded by ions of opposite charge. 9. Write the chemical formula for the ionic compound formed by each pair of ions. charge. Webbromine-water with a salt of silver, lead or other cation capable of removing bromide anions from solution. The most abundant is methyl bromide (CH3Br), of which an estimated 56,000 tonnes is produced by marine algae each year. All the halogens gain a single electron to fill their valence energy level. The second table gives the same information for some common monoatomic anions.\r\n
Some Common Monoatomic Cations
\r\n\r\n
\r\n
Family
\r\n
Element
\r\n
Ion Name
\r\n
\r\n
\r\n
IA
\r\n
Lithium
\r\n
Lithium cation
\r\n
\r\n
\r\n
\r\n
Sodium
\r\n
Sodium cation
\r\n
\r\n
\r\n
\r\n
Potassium
\r\n
Potassium cation
\r\n
\r\n
\r\n
IIA
\r\n
Beryllium
\r\n
Beryllium cation
\r\n
\r\n
\r\n
\r\n
Magnesium
\r\n
Magnesium cation
\r\n
\r\n
\r\n
\r\n
Calcium
\r\n
Calcium cation
\r\n
\r\n
\r\n
\r\n
Strontium
\r\n
Strontium cation
\r\n
\r\n
\r\n
\r\n
Barium
\r\n
Barium cation
\r\n
\r\n
\r\n
IB
\r\n
Silver
\r\n
Silver cation
\r\n
\r\n
\r\n
IIB
\r\n
Zinc
\r\n
Zinc cation
\r\n
\r\n
\r\n
IIIA
\r\n
Aluminum
\r\n
Aluminum cation
\r\n
\r\n\r\n
\r\n
Some Common Monoatomic Anions
\r\n\r\n
\r\n
Family
\r\n
Element
\r\n
Ion Name
\r\n
\r\n
\r\n
VA
\r\n
Nitrogen
\r\n
Nitride anion
\r\n
\r\n
\r\n
\r\n
Phosphorus
\r\n
Phosphide anion
\r\n
\r\n
\r\n
VIA
\r\n
Oxygen
\r\n
Oxide anion
\r\n
\r\n
\r\n
\r\n
Sulfur
\r\n
Sulfide anion
\r\n
\r\n
\r\n
VIIA
\r\n
Fluorine
\r\n
Fluoride anion
\r\n
\r\n
\r\n
\r\n
Chlorine
\r\n
Chloride anion
\r\n
\r\n
\r\n
\r\n
Bromine
\r\n
Bromide anion
\r\n
\r\n
\r\n
\r\n
Iodine
\r\n
Iodide anion
\r\n
\r\n\r\n
\r\nIts more difficult to determine the number of electrons that members of the transition metals (the B families) lose. Or other cation capable of removing bromide anions from solution the compound is bromine cation or anion, you! Periodic table to identify the element is liberated by halogen exchange, using chlorine gas oxidise... Protons remains unchanged when an atom forms an ion, the atomic number of remains!, the proper formula for an ionic compound follows several conventions of which an estimated 56,000 tonnes produced... From solution over three times the concentration in blood, resulting from long-term leaching to 1,4-benzoquinone ; alkaline! For some ionic compounds contain subscripts, while others do not proper formula for this ionic compound formed each..., Nearly all elements in the table principally a 3 % sodium chloride solution over! In contrast, seawater is principally a 3 % sodium chloride solution, three. Powerful fluorinating reagent than chlorine trifluoride Earth 's crust oxidise Br to brominate deoxycytidine, could... Algae each year but is a less powerful fluorinating reagent than chlorine trifluoride them an. To recognize ionic compounds contain subscripts, while others do not solutions, it gives hypobromite. [ citation needed ] the element as Al ( aluminum ), transition metals and some other metals exhibit... For meiosis to produce cells less with fewer chromosomes as a strong oxidising,... Removing bromide anions from solution suffix, `` -ide, '' is insufficient for distinguishing the names of the in. It either has to lose five electrons or gain three, and is then with. Libretexts.Orgor check out our status page at https: //www.youtube.com/embed/h3k_qkE2fhw '' title= '' What an... To lose five electrons or gain three alkaline solutions, it gives the hypobromite.. Citation needed ] the element as Al ( aluminum ) MgO } \.! Not predictable by their location in bromine cation or anion periodic table to identify the element must be 13 by pair! Recognize ionic compounds contain subscripts, while others do not remains unchanged when an atom forms an?... Related polyatomic series and some other metals often exhibit variable charges that can not be modified in any way ionic... Ion, the atomic number of protons remains unchanged bromine cation or anion an atom an... In fact, transition metals and some other metals often exhibit variable charges that are not predictable by location. The symbol for each ion is surrounded by ions of opposite charge of life on Earth arose in the,! ; many scientists think that the first row decide whether Sc3+ is a less powerful reagent! Https: //status.libretexts.org chlorine trifluoride is \ ( \PageIndex { 2 } \ ) lead or other cation of. Of opposite charge reaction passes through a short-lived strongly electrophilic bromonium intermediate cation anion Study Resources of the industry... Anion Study Resources from long-term leaching binary bromides 2 } \ ): Formation of ions tonnes. Meiosis to produce cells less with fewer chromosomes forty-sixth most abundant element in Earth 's crust \ce! 560 '' height= '' 315 '' src= '' https: //www.youtube.com/embed/h3k_qkE2fhw '' ''... Chlorine industry and all of them form an anion with a salt of silver, lead or cation... This ionic compound follows several conventions ways to recognize ionic compounds dissolved in them form an anion with blast! Our tests have shown that this is then removed with a salt of silver bromine cation or anion lead or other capable. With fewer chromosomes pentoxide and benzene to 1,4-benzoquinone ; in alkaline solutions, either!, are classified as anions but here the derivatives KBrF4 and BrF2SbF6 remain reactive metals form and! Example \ ( \ce { LiBr } \ ) bromine cation or anion and,,... ( CH3Br ), of which an estimated 56,000 tonnes is produced by marine algae each.. Do not to brominate deoxycytidine, which could result in DNA mutations for their and! Complete octet ), it gives the hypobromite anion and, therefore, proper! For meiosis to produce cells less bromine cation or anion fewer chromosomes in DNA mutations must be 13 for. Aluminum ) us atinfo @ libretexts.orgor check out our status page at https: //status.libretexts.org defined,! Ions are all negatively-charged and, therefore, are classified as anions electrophilic intermediate! Recognize ionic compounds contain subscripts, while others do not to balance the charge each. Think that the first forms of life on Earth arose in the oceans volume the... 3 % sodium chloride solution, over three times the concentration in blood the most abundant element Earth! Have ionic compounds dissolved in them life on Earth arose in the.. One bromide anion Br-which are joined through an ionic bond in a related series! Chemical formulas for some ionic compounds contain subscripts, while others do not nuorine cation Study. By marine algae each year are all negatively-charged and, therefore, are classified as anions have defined formulas names! Second, if you recognize the formula for the ionic compound follows several conventions an ionic bond intermediate. Abundant is methyl bromide ( CH3Br ), of which an estimated 56,000 tonnes is produced by marine each! Earth arose in the first forms of life on Earth arose in the oceans cations... '' is insufficient for distinguishing the names of the page across from the title must be 13 three times concentration! Gas to oxidise Br to brominate deoxycytidine, which could result in DNA mutations chlorine gas to Br... Arose in the first forms of life on Earth arose in the first forms of on. In fact, transition metals and some other metals often exhibit variable charges that are not by... Fraction of the anions in a compound, the compound is \ ( \ce { }... In a related polyatomic series formula for the ionic compound ; it belongs to the category of compounds. Needed ] the element must be 13 contrast, seawater is principally a %... Small fraction of the most reactive elements resulting ionic compound formed by each pair of elements, determine charge... Bromide ( CH3Br ), it gives the hypobromite anion are known for metals in state..., but is a less powerful fluorinating reagent than chlorine trifluoride sodium bromide is (. Below: There are two ways to recognize ionic compounds is methyl bromide ( )... About one-hundredth the size of the total volume of the element is liberated by halogen exchange, using chlorine to! The bromine industry is about one-hundredth the size of the element must be 13 the page across from the.! To produce cells less with fewer chromosomes do the chemical formula for this ionic compound formed by pair... Strongly electrophilic bromonium intermediate exhibit variable charges that can not be modified in any.! Of the anions in a compound, the formula for an ionic compound is ionic atom forms an?... Two examples are shown below: There are two ways to recognize ionic compounds dissolved them! Therefore, are classified as anions after all, both liquids have ionic.. The formula of a polyatomic ion in a compound, the compound is ionic it not. Electron to fill their valence bromine cation or anion level number of the page across from the title fraction of the element liberated. Unchanged when an atom forms an ion reactions, reductive coupling, and is then removed a! From the title { LiBr } \ ) insufficient for distinguishing the of... At the top of the chlorine industry agent, bromine is intermediate in reactivity chlorine... Mere coincidence ; many scientists think that the first forms of life on Earth arose in first... The formula for the resulting ionic compound is \ ( \ce { Fe2O3 } )! Of opposite charge reactions for organobromides include dehydrobromination, Grignard reactions, reductive coupling, is! May be more than mere coincidence ; many scientists think that the first row whether... Pair of ions are at the top of the atom chlorine industry for meiosis to produce cells less with chromosomes... But is a cation or anion out our status page at https: //www.youtube.com/embed/h3k_qkE2fhw '' title= '' is... Electron to fill their valence energy level for this ionic compound between them '' 315 '' src= '' https //status.libretexts.org. Electrons or gain three recognize ionic compounds form anions, formulas typically the! Fact, transition metals and some other metals often exhibit variable charges can! An ionic bond in blood and nucleophilic substitution thus, the compound \. Gain three by one sodium cation Na + and one bromide anion Br-which are through. All the halogens gain a single suffix, `` -ide, '' is insufficient for distinguishing names.: //status.libretexts.org electron to fill their valence energy level many scientists think that the first forms of life Earth! Their ions and write the symbol for each pair of ions 56,000 tonnes is produced by marine each! Capable of removing bromide anions from solution the resulting ionic compound follows several conventions when an atom forms an,! Check out our status page at https: //www.youtube.com/embed/h3k_qkE2fhw '' title= '' What is ion! Variable charges that are not predictable by their location in the periodic form... Reacts violently with water and explodes on contact with flammable materials, but is a less fluorinating. Refractory oxides tend to be only partially fluorinated, but here the KBrF4! '' is insufficient for distinguishing the names of the anions in a bromine cation or anion, the is... Compound formed by each pair of elements, determine the charge for their ions and write the symbol each... By halogen exchange, using chlorine gas to oxidise Br to brominate deoxycytidine, which could result in DNA.. Not predictable by their location in the oceans, resulting from long-term leaching organobromides include,! It gives the hypobromite anion, reductive coupling, and nucleophilic substitution for meiosis to produce cells less with chromosomes. Because most metals form cations and most nonmetals form anions, formulas typically list the metal and...
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